Mention liquid metal, and people immediately think of mercury. After all, it is the only metal that isn't solid at room temperature. Well, not quite-it's the only pure metal, but there are many alloys (mixtures of metals) that will melt well below that point. For example, the mercury-filled fever thermometers that children were told not to play with in the 1950s and '60s have been replaced by virtually identical ones containing the far less toxic Galinstan, a patented liquid alloy of gallium, indium and tin.
Those who were kids in that era may also remember playing with another low-melting-point alloy: trick spoons that melted when you tried to stir your coffee with them. These were made with a blend that, no surprise, was highly toxic; it typically contained cadmium, lead, mercury or all three. But, as it happens, it's possible to make alloys that liquefy in a hot drink using safer components.
A few months ago I created a batch of these prank spoons as a gift for my friend and fellow element buff Oliver Sacks (author of Awakenings and Uncle Tungsten). I cast jewelers' molding rubber around a fancy spoon to form the mold. Then I looked up the formula for an alloy that would melt at 140°F, roughly the temperature of a cup of hot coffee, and found this one: 51 percent indium, 32.5 percent bismuth and 16.5 percent tin.
After the spoon turns to a puddle at the bottom of the cup, you can pour off the liquid and touch the metal, feeling the weird sensation of it hardening around your fingertip. When Sacks has used up all his spoons, he can easily recover the metal, melt it again over a cup of hot water, pour it into the mold, and make new ones-the trick-spoon circle of life.
So why can't you buy these nontoxic prank utensils in toy stores, as you could the toxic versions of years past? Price. Indium costs about three times as much as silver. (I get mine from a bulk supplier in China.) Using gallium, you can make alloys that melt in lukewarm water or even in your hand, but it's more expensive than indium, and it tends to stain the glass and discolor skin. Unfortunately, no alloy replicates the low cost, bright shine and nonstick fun of mercury. Too bad we know now that playing with it for too long can give you brain damage. |
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